Fertilizer industry solution whitepapers

Since more than a decade, Badotherm specializes in specific measurements solutions for the urea and fertilizer industry, due to their very demanding process conditions and specific corrosion challenges. With several case studies and whitepapers, we like to share our experiences and help solve the challenges that the industry is facing and have better and long lasting and durable pressure and level measurements with diaphragm seals.

Pressure measurement in Zirconium for high pressure carbamate gas line

A urea plant (identity confidential) has installed in a high pressure and high temperature carbamate gas line a BADOTHERM EXT Full Zirconium diaphragm seal pressure measurement. The material of construction of the pipeline is duplex 2205, the pipeline is electrically traced and operates at 150 bar and 190oC. The nozzle for the pressure measurement is located in the top of a horizontal part of the pipeline. One can state these are really extreme process conditions, with typically heavy corrosion problems due to ammonium carbamate.

Other similar applications are:
– Measure the Synthesis Pressure in the high pressure carbamate gas line close to the safety valve in any urea plant
– Measure the Synthesis Pressure at any other location in the synthesis section of any urea plant like ammonia feed, CO2 feed, air supply, etc.
– Measure the Liquid Level in the High Pressure Scrubber of a STAMICARBON urea plant.
– Now it becomes attractive to check the feasibility to measure also other liquid level applications like the high pressure separator in a SAIPEM urea plant.

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Points of Attention for Pressure measurements with Diaphragm Seals in UREA Plants

This document summarizes the points of attention when applying pressure measurements with pressure transmitter assembled with diaphragm seals in urea plants. Its content is based on evaluating several troubleshoot cases in the industry.

Pressure measurements with diaphragm seals is considered a very robust measurement solution to protect the pressure instrument from the often harsh process conditions. However, the diaphragm seal system needs to be engineered and installed properly. Firstly, this means selecting the best suitable diaphragm seal type and diaphragm size, suitable filling fluid to match temperature and withstand possible vacuum and the suitable material of the wetted
parts of the diaphragm seal, which is best compatible / corrosion resistant with the process.

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Reliable pressure and Level Diaphragm Seal measurements in UREA plants

Measuring pressures, levels and delta-P’s in UREA plants is a real challenge. Crystallization, erosion and corrosion risks have to be taken care of. Typically diaphragm (or membrane) type of measurements are
applied nowadays but its lifetime is typically limited (e.g. max one year). After this period, these diaphragms face corrosion problems and mostly needs to be replaced. This means the UREA plant needs to shut down mostly unexpected leading to significant costs in production loss.

More and more UREA plants target continuous running periods between planned turnarounds of two, four to even six years. Sometimes one is able to keep the plant in operation but one needs to operate the plant under non optimum process conditions. Such a situation also leads to a significant negative financial impact as illustrated in this paper. BADOTHERM is a well-known manufacturer of reliable diaphragm seal type pressure, level and delta-P measurements suitable for all UREA process technologies.

Significant costs can be avoided and additional profits can be gained with the BADOTHERM Diaphragm Seals mounted to Pressure Transmitters, for pressure, level or delta-P measurements. Badotherm has several designs and materials available meeting the specific requirements of the UREA industry.

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Diaphragm Seal solution for prevention of corrosion issues in CO2 removal systems Ammonia

A release of Benfield Solution (Hot Potassium carbonate) and Syngas from the level bridle of the CO2 Absorber in the Ammonia Plant resulted in a plant shutdown and subsequently a fire. fortunately, there were no personnel and damaged was limited in this case, however, construction works, including demolition, material procurement, fabrication, NDE and insulation to more than a week.

Attention to the material specifications of the specific components of the level pressure measurement are important. In this specific situation, the upgrade to tantalum wetted parts material for the diaphragm seals could have avoided this critical situation to occur.

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Why accessibility is the number one factor to look for in a supplier

Everyone managing a part of a production plant in the petro-chemical industry wants to maintain a continuous and high output, safely and efficiently. However, (un)scheduled downtime due to pressure measurement failure or unreliable or failing measurements seems unpreventable and are cumbersome to fix, especially with pressure being the most measured entity.
To what extent those issues slow your processes down and consume your valuable time depend heavily on who you select to be your service provider. It is our strong conviction that the number one factor is accessibility. Because effective communication between you and your supplier results in the right engineering and failure could become a problem of the past.
We’ll tell you more about the importance of accessibility in this whitepaper.

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Improving Safety and Reliability of High-Pressure Measurements in Snamprogetti UREA plants

Profertil, a leading UREA producer, was facing continuous and recurring issues with pressure measurements in the high pressure urea synthesis section of their Bahia Blanca plant in Argentina. Despite attempts to resolve the issues, measurement failures continued to occur, putting their operations at risk and preventing them from achieving their objective of increasing production
output and reducing energy consumption. To address this challenge, they turned to Badotherm in 2017, a specialist in the field of diaphragm seal technology. Through close collaboration and an unstoppable drive to engineer ultimate solutions, Badotherm was able to build a diaphragm seal system that solved Profertil’s problems and delivered unrivalled performance.

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Case Study: Delivering perfect plantstops for enhanced performance

Yara International is one of the leading fertilizer production companies worldwide. As part of Yara’s sustainability ambitions to reduce its own emissions and improve productivity at its production sites, operational excellence and continuous process improvement is key. All with the aim of improving reliability at plants and optimizing end-to-end business processes.

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Overcoming Challenges with Tantalum Lining and Extended type Diaphragm Seal

As industry specialists in the design and manufacturing of diaphragm seal systems for UREA applications, we recognize the critical importance of addressing safety risks and reliability issues. This case study aims to inform market specialists about the potential risks associated with the use of tantalum linings or sleeves on extended type diaphragm seals in high-pressure synthesis sections of UREA plants. Join us as we explore a near miss safety incident, break down the disadvantages of this execution and highlight the superiority of zirconium material diaphragm seal as an alternative, and conclude with a call to embrace safer solutions. Together, we can foster a safer and more reliable UREA industry.

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